Macrocyclization on the fullerene core: Direct regio‐and diastereoselective multi‐functionalization of [60] fullerene, and synthesis of fullerene‐dendrimer derivatives

…, T Habicher, R Kessinger, F Cardullo… - Helvetica chimica …, 1997 - Wiley Online Library
The macrocyclization between buckminsterfullerene, C 60 , and bis‐malonate derivatives in
double Bingel reaction provides a versatile and simple method for the preparation of …

Identification and characterization of novel NMDA receptor antagonists selective for NR2A-over NR2B-containing receptors

…, SA Senar-Sancho, L Guiral, F Cardullo - … of Pharmacology and …, 2010 - ASPET
NR1/NR2A is a subtype of N-methyl-d-aspartate receptors (NMDARs), which are glutamate
and glycine-gated Ca 2+ -permeable channels highly expressed in the central nervous …

Routes to Dendritic Networks: Bis‐Dendrimers by Coupling of Cascade Macromolecules through Metal Centers

…, R Güther, CN Moorefield, F Cardullo… - … Edition in English, 1995 - Wiley Online Library
The specific linking of two dendrimers is achieved by incorporating terpyridine moieties at
precise locations in cascade molecules. Metal complex formation then enables nonrandom …

Bis‐ through Tetrakis‐Adducts of C60 by Reversible Tether‐Directed Remote Functionalization and systematic investigation of the changes in fullerene properties as …

F Cardullo, P Seiler, L Isaacs… - Helvetica chimica …, 1997 - Wiley Online Library
By the tether‐directed remote functionalization method, a series of bis‐ to hexakis‐adducts
of C 60 , ie, 1–7 (Fig. 1), had previously been prepared with high regioselectivity. An efficient …

Stable langmuir and langmuir− blodgett films of fullerene− glycodendron conjugates

F Cardullo, F Diederich, L Echegoyen, T Habicher… - Langmuir, 1998 - ACS Publications
The amphiphilic C 60 -dendrimer conjugates 1 and 2 with one and two glycodendron
headgroups, respectively, form stable, ordered monomolecular Langmuir layers at the air−water …

Metallomicellanols: incorporation of ruthenium (II)–2, 2′: 6′, 2 ″-terpyridine triads into cascade polymers

GR Newkome, F Cardullo, EC Constable… - Journal of the …, 1993 - pubs.rsc.org
Facile alkoxylation of 4′-chloro-2,2′ :6′,2″-terpyridine with the mono- and tri-hydroxylic
cascade (dendritic) building blocks, 4-(3-hydroxypropyl)-4-(3-benzyloxypropyl)-1,7-bis(…

Redox Characteristics of Covalent Derivatives of the Higher Fullerenes C70, C76, and C78

…, M Rüttimann, J Crassous, F Cardullo… - Journal of the …, 1998 - ACS Publications
The electrochemical properties of covalent derivatives of the higher fullerenes C 70 , C 76 ,
C 2 v -C 78 , and D 3 -C 78 , bearing bis(alkoxycarbonyl)methano addends, were …

Thermotropic behaviour of covalent fullerene adducts displaying 4-cyano-4′-oxybiphenyl mesogens

N Tirelli, F Cardullo, T Habicher, UW Suter… - Journal of the …, 2000 - pubs.rsc.org
The synthesis of the covalent fullerene derivatives 2, 3 and 4 with an increasing number (2,
4 and 6) of 4-cyano-4′-oxybiphenyl mesogenic groups is described. The thermotropic …

Synthesis of a Fullerene [60] Cryptate and Systematic Langmuir‐Blodgett and Thin‐Film Investigations of Amphiphilic Fullerene Derivatives

U Jonas, F Cardullo, P Belik, F Diederich… - … A European Journal, 1995 - Wiley Online Library
The synthesis of the first fullerene cryptate 7 with a sodium ion bound to a benzo[2.2.2]cryptand
covalently attached to a methanofullerene[60] is described. The amphiphilic properties of …

Synthesis and structure–activity relationships of α-amino-γ-lactone ketolides: a novel class of macrolide antibiotics

…, D Andreotti, S Biondi, F Cardullo… - ACS Medicinal …, 2014 - ACS Publications
An efficient synthesis of α-amino-γ-lactone ketolide (3) was developed, which provided a
versatile intermediate for the incorporation of a variety of aryl and heteroaryl groups onto the C-…