The preparation of the species [(NH 3) 5Ru] 2pyr 4+.+> c6" 1-in solution is described, as is
that of solid phases containing each of the three cations. The species of intermediate …

… This is not a factor for H2+ in the gas phase but would be a serious one were H,f immersed
in … (The state H30+ + H is in all likelihood more stable than Hi(aq).) The extent of electron …

… 4 and the methyl C–H bonds of methyl bisulate when a solution of CH 3 OSO 3 H (0.2 M) …
limiting rate of H/D exchange of methyl bisulfate (if we assume that all C–H activation events of …

6 has been corrected for the effect9 of AF). When allow-ance is made for the energy required
to bring the reac-tants together, the second-order rate constant referred to would convert to a …

… done as described by Isied and Taube.1 Solids, analyzing as summarized in Chart I, … The
reaction was allowed to continue for 4 h in the dark under argon. At the end of this time, 20 ml …

The ion [Ru (NH3) sH2S] 2+ has been characterized, and salts containing it havebeen
prepared. The value of pK\for the species is 4.0, andthe equilibrium constant for the reaction of …

The experience gained in general chemistry or qualitative analysis with re-actions in which
metal-ion complexes are formed or dissociated is limited in scope, and often leaves the …

The techniques of pulse and cyclic voltammetry havebeen applied to the determination of E2-Efor
two-step electrochemical charge transfers. A simple theory has been derived for the …

… Taube. The conclusion is inescapable that despite the agreement noted by Haim and Taube
… HzO—DzO solvent change: D replaces H in the bridging groups HO‘ and H20, D replaces H …

Several topics are dealt with in discussing the reactions of molecular oxygen, but a common
goal is pursued in each: to try to understand the reactions in terms of the fundamental …