Low-coordinate mononuclear lanthanide complexes as molecular nanomagnets
The discovery that some bis-(phthalocyaninato)lanthanide complexes are molecular magnets
triggered interest in lanthanide ion complexes. Theoretical and experimental observations …
triggered interest in lanthanide ion complexes. Theoretical and experimental observations …
Role of Coordination Number and Geometry in Controlling the Magnetic Anisotropy in FeII, CoII, and NiII Single‐Ion Magnets
… The same colour code has been used throughout the review except in Figure 2 g. … (f) X-ray
structure of complex (25) along with the NEVPT2 computed g z axis. (g) NEVPT2-LFT …
structure of complex (25) along with the NEVPT2 computed g z axis. (g) NEVPT2-LFT …
Strategies to quench quantum tunneling of magnetization in lanthanide single molecule magnets
… where g x and g y are transversal g factors of the doublet, corresponding to perpendicular
directions to its main magnetic axis. H x and H y are respective components of the magnetic …
directions to its main magnetic axis. H x and H y are respective components of the magnetic …
[HTML][HTML] An air-stable Dy (III) single-ion magnet with high anisotropy barrier and blocking temperature
… The computed g-tensors of the ground state KDs for 1 is purely Ising in nature (g xx , g yy
= 0.4 × 10 −4 and g zz = 19.86) as the g zz value reaches close to ∼20 and the transverse …
= 0.4 × 10 −4 and g zz = 19.86) as the g zz value reaches close to ∼20 and the transverse …
Synthesis and Characterization of Heterometallic {Cr7M} Wheels
… For example, 6 gives a pair of transitions at g xy =1.781 and g z =1.740 (Figure 3 a). … low
g value can be justified based on the vector coupling approach, 10 assuming g Cr =1.99 and g …
g value can be justified based on the vector coupling approach, 10 assuming g Cr =1.99 and g …
Insight into D6h Symmetry: Targeting Strong Axiality in Stable Dysprosium(III) Hexagonal Bipyramidal Single‐Ion Magnets
…, ER Martí, C Wilson, G Rajaraman… - Angewandte Chemie …, 2019 - Wiley Online Library
… It is important to note the relatively larger g xx /g yy values … 2, g xx =0.677, g yy =1.923, g zz
=12.687 for 1; g xx =0.614, g yy =1.695, g zz =12.766 for 2 and g xx =0.117, g yy =0.731, g zz =…
=12.687 for 1; g xx =0.614, g yy =1.695, g zz =12.766 for 2 and g xx =0.117, g yy =0.731, g zz =…
Variability in P-glycoprotein inhibitory potency (IC50) using various in vitro experimental systems: implications for universal digoxin drug-drug interaction risk …
…, A Patel, L Podila, E Plise, G Rajaraman… - Drug metabolism and …, 2013 - ASPET
A P-glycoprotein (P-gp) IC 50 working group was established with 23 participating
pharmaceutical and contract research laboratories and one academic institution to assess …
pharmaceutical and contract research laboratories and one academic institution to assess …
Enhancing the effective energy barrier of a Dy (iii) SMM using a bridged diamagnetic Zn (ii) ion
…, SK Langley, KS Murray, G Rajaraman… - Chemical …, 2014 - pubs.rsc.org
… that the local g-tensors in … [g xx = 0.02, g yy = 0.04 and g zz = 18.82], while the g-tensors
for 2a and 2b are computed to be [g xx = 0.020, g yy = 0.036, g zz = 19.443] and [g xx = 0.081, g …
for 2a and 2b are computed to be [g xx = 0.020, g yy = 0.036, g zz = 19.443] and [g xx = 0.081, g …
Discovery of N-(4-(2,4-Difluorophenoxy)-3-(6-methyl-7-oxo-6,7-dihydro-1H-pyrrolo[2,3-c]pyridin-4-yl)phenyl)ethanesulfonamide (ABBV-075/Mivebresib), a Potent …
…, DH Albert, TJ Magoc, G Rajaraman… - Journal of medicinal …, 2017 - ACS Publications
… To this solution was added sodium hydride (1.18 g, 1.96 g of 60% dispersion in oil, 49.0
mmol), and the reaction mixture was stirred for 10 min. p-Toluenesulfonyl chloride (9.35 …
mmol), and the reaction mixture was stirred for 10 min. p-Toluenesulfonyl chloride (9.35 …
A family of manganese rods: Syntheses, structures, and magnetic properties
… Complex 1, [Mn 12 O 4 (OH) 2 (PhCOO) 12 (thme) 4 (py) 2 ], has an S = 7 ground state
with the parameters g = 1.98 and D = −0.13 K. Complex 2, [Mn 8 O 4 ((CH 3 ) 3 CCO 2 ) 10 (thme) …
with the parameters g = 1.98 and D = −0.13 K. Complex 2, [Mn 8 O 4 ((CH 3 ) 3 CCO 2 ) 10 (thme) …