A study of the reaction of different phenol substrates with nitric oxide and peroxynitrite
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Plant-inspired gallolamine catalytic surface chemistry for engineering an efficient nitric oxide generating coating
2018, Acta BiomaterialiaCitation Excerpt :The ignorable influence of phenolic hydroxyl groups retained on GA/HD surface on NO generation might be ascribed to the huge disparity in their amounts between phenolic hydroxyl groups and NO generated from GA/CySA. Messeguer et al. have reported that NO could react with phenolic compounds [27]. With the consideration of this, we thereby further investigated the possible effects of the retention of the phenolic hydroxyl groups on the coating prepared by 1:0.25 M ratio of GA and hexamethylenediamine (HD) instead of CySA (this coating marked as GA/HD) on NO generated by GA/CySA prepared by 1:4 M ratio of GA and CySA.
Novel tocopheryl compounds XXIV. Studies into the nitrosation chemistry of γ-tocopherol: preparation of 5-nitroso-γ-tocopherol via an organomercury derivative of vitamin E
2007, TetrahedronCitation Excerpt :5-Nitro-γ-tocopherol (7) as well as the ortho-quinone α-tocored (8) are side products in the nitrosation chemistry of γ-tocopherol. The analytical data reported in the literature were not consistent for both tocored36–39 and the nitro derivative.5–7,9,10 In the case of the former many reports date before the 1960s and include UV spectra, but no NMR data nor proof of purity, in the case of the latter conclusions on the nature of the compound were often based solely on UV spectra and were thus—due to the equilibria and side reactions described above—quite erroneous.
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